4.8 Article

It is thiazolidene-2-imine and not imidazole-2-thione as the reaction product of 1-benzoyl-3-phenylthiourea with Br2/enolizable ketone

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ORGANIC LETTERS
Volume 8, Issue 23, Pages 5397-5399

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AMER CHEMICAL SOC
DOI: 10.1021/ol062371b

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[GRAPHICS] The products obtained by the reaction of benzoyl-3-phenylthioureas with bromine and enolizable ketones in the presence of triethylamine are not imidazole-2-thione derivatives as reported (Org. Lett. 2003, 5, 1657 - 1659) rather they are thiazolidene-2-imine derivatives.

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