Journal
ORGANIC LETTERS
Volume 8, Issue 23, Pages 5183-5186Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol061682j
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- NIGMS NIH HHS [GM62824] Funding Source: Medline
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Epoxidation of highly strained cyclobutenes followed by thermal rearrangement provides a new entry into oxepine-containing bicyclo[5.3.0] ring systems. In contrast to the rearrangement of the corresponding cyclopropanated systems, the strained epoxides in this study are believed to fragment through two competing pathways leading to a mixture of diastereomeric 5-7 ring systems.
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