Journal
ORGANIC LETTERS
Volume 8, Issue 23, Pages 5239-5242Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol062000v
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A new mechanism involving a diimine intermediate is proposed for vicinal diamine-catalyzed synthesis of warfarin. Decreasing the NCCN dihedral angle by varying the diamine results in an increase in the enantioselectivity of warfarin synthesis.
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