Journal
ORGANIC LETTERS
Volume 8, Issue 23, Pages 5271-5273Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol062116r
Keywords
-
Categories
Ask authors/readers for more resources
A TiCl4-promoted tandem semipinacol/Aube's type intramolecular Schmidt reaction of alpha-siloxy-epoxy-azide has been designed and developed to be a general method for efficient construction of azaquaternary carbon units. As applicable examples, some key tricyclic azaquaternary skeletons incorporated in many important alkaloids, such as cephalotaxine, stemonamine, erythrinan, and homoerythrinan alkaloids, have been constructed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available