Journal
ORGANIC LETTERS
Volume 8, Issue 23, Pages 5303-5305Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol062107i
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[GRAPHICS] Treatment of an N-4-pentenyl or N-5-hexenyl urea with a catalytic 1: 1 mixture of a gold(I) N,N-diarylimidazol-2-ylidine complex and AgOTf at or near room temperature leads to intramolecular exo-hydroamination to form the corresponding nitrogen heterocycle in excellent yield.
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