4.7 Article

NaCl-type frameworks of [M(pyrazine)2NO2]ClO4 (M) Co, Cu), the first examples containing μ1,3-nitrito bridges showing antiferromagnetism

Journal

INORGANIC CHEMISTRY
Volume 45, Issue 23, Pages 9148-9150

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic060759x

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Two new 3D NaCl-type frameworks of [M(pyrazine)(2)NO2]ClO4 (M = Co, Cu), consist of (4, 4) sheets of metal-pyrazine connected by mu(1,3)-nitrito, representing the first examples of mu(1,3)-nitrito bridges and exhibiting antiferromagnetism.

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