Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2006, Issue 22, Pages 5103-5109Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200600584
Keywords
carbenes; shift reagents; ionic liquids; imidazolinium salts
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The behavior of new enantiopure imidazolinium salts bearing two hydroxy-containing substituents as chiral shift reagents and as carbene precursors for diethylzinc addition to aldehydes is presented. The new hydroxy-containing imidazolinium salts can be prepared in a few steps from amino alcohols and qualify as new tridentate ligands and ionic liquids. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006.
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