4.7 Article Proceedings Paper

Temperature versus density effects in glassforming liquids and polymers: A scaling hypothesis and its consequences

Journal

JOURNAL OF NON-CRYSTALLINE SOLIDS
Volume 352, Issue 42-49, Pages 4888-4894

Publisher

ELSEVIER
DOI: 10.1016/j.jnoncrysol.2006.05.037

Keywords

glass formation; glass transition; pressure effects; liquid crystals and molecular liquids; polymers and organics; viscosity and relaxation; fragility

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We discuss the validity and the outcome of a scaling hypothesis proposed by us some years ago, according to which the influence of the density on the slowing down of flow and relaxation in glassforming liquids and polymers is described through a single effective interaction energy E.(p). We stress the formal consequences and the physical meaning of the scaling. (c) 2006 Elsevier B.V. All rights reserved.

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