Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 259, Issue 1-2, Pages 205-212Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2006.06.004
Keywords
nickel; phosphine; N-heterocyclic carbene; C-C coupling; Grignard
Categories
Ask authors/readers for more resources
Two new zwitterionic nickel(II) complexes, bearing phosphine/imidazolium ligands, have been prepared. Their catalytic activity, and the activity of an analogous Ni(II) complex, previously described by us, has been evaluated with a range of aryl chlorides, an aryl bromide and arylmagnesium halides. The catalytic activity is related to the length of the tether between the carbene and phosphine moieties. Thus the catalysts possessing a six-membered metallacycle are more active than that having a seven-membered metallacycle. Changing from a mesityl (Mes) to a 2,6-diisopropylphenyl (DIP) on the imidazole ring does not strongly influence the activity. The three complexes show moderate to very good activities with most substrates, and enhanced selectivities compared to previously published Ni(II)/N-heterocyclic carbene systems. The low activity observed with 4-chlorobenzotrifluoride seems to be related to the presence of a phosphine on the ligands. (c) 2006 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available