Journal
ORGANOMETALLICS
Volume 25, Issue 24, Pages 5829-5831Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om060666n
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Readily available N-heterocyclic platinum complexes provide active catalytic species for 1,2-diboration and anticipate a wide range of applications in alkenes and alkynes. Unprecedented catalytic B-B addition of heteroatom-containing substrates provided high selectivity into organosulfur-diboronate esters. Their in situ basic oxidation afforded the desired 1,2-dihydroxysulfones in high yields.
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