4.5 Article

Alk-2-ynyl trimethylsilyl chalcogenoethers by nucleophilic substitution of propargyl bromides

Journal

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 22, Pages 4616-4620

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200600583

Keywords

Chalcogens; silicon; propargyl complexes

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Lithium (trimethlsilyl)chalcogenolates have been generated and used to prepare a series of alk-2-ynyl trimethylsiyl chalcogenoethers from the corresponding propargyl bromides in good yeild. The thermal decomposition of the telluroethers has also been studied. ((c) Wiiley-VCH Verlag GMBH & Co. KGaA).

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