Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 125, Issue 19, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.2388273
Keywords
-
Ask authors/readers for more resources
One-dimensional alignment of molecules in the adiabatic limit, where the pulse duration greatly exceeds the molecular rotational periods, is studied experimentally. Four different asymmetric top molecules (iodobenzene, p-diiodobenzene, 3,4-dibromothiophene, and 4,4(')-dibromobiphenyl), rotationally cooled through a high pressure supersonic pulsed valve, are aligned by a 9-ns-long pulse. Their orientations are measured through Coulomb explosion, induced by a 130-fs-long pulse, and by recording the direction of the recoiling ions. The paper focuses on the crucial role of the initial rotational temperature for the degree of alignment. In particular, we show that at molecular temperatures in the 1 K range very strong alignment is obtained already at intensities of a few times 10(11) W/cm(2) for all four molecules. At the highest intensities (similar to 10(12) W/cm(2)) the molecules can tolerate without ionizing < cos(2) theta >>= 0.92 in the case of iodobenzene. This is the strongest degree of alignment ever reported for any molecule. (c) 2006 American Institute of Physics.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available