Journal
ORGANIC LETTERS
Volume 8, Issue 24, Pages 5617-5620Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol062357z
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The first synthesis of sulfonamide and sulfonate analogues of a sulfated carbohydrate in which the ester oxygen of the sulfate is replaced with a CHF or CF2 group is reported. This was accomplished by electrophilic fluorination of the protected sulfonate and sulfonamide precursors.
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