Journal
TETRAHEDRON LETTERS
Volume 47, Issue 48, Pages 8571-8574Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.09.108
Keywords
fullerene; cyclodextrin; anions; supramolecular chemistry
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A novel supramolecular inclusion complex of alpha-CD/C-60 was synthesized using anionic C-60. The reaction progress was monitored in situ by visible and near-IR spectroscopy. The obtained complex was characterized by UV-vis, C-13 NMR, MALDI-TOF, and cyclic voltammetry. The induction and dispersion forces are considered to be the major driving forces for the formation of a resulting alpha-CD/C-60(.-) inclusion complex. (c) 2006 Elsevier Ltd. All rights reserved.
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