4.5 Article

4-O-acetyl-3-O-tert-butyldimethylsilyl-L-rhamnal:: a building block in the stereoselective synthesis of 2-deoxy-α-L-rhamnopyranosides

Journal

CARBOHYDRATE RESEARCH
Volume 341, Issue 16, Pages 2702-2707

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2006.09.007

Keywords

glycals; 2-deoxyglycosides; stereoselective synthesis

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The stereoselective synthesis of 2-deoxy-alpha-L-glycosides by addition of various acceptors to 4-O-acetyl-3-O-tert-butyldimethylsilyi-L-rhamnal promoted by triphenylphosphine-hydrogen bromide is developed. (c) 2006 Elsevier Ltd. All rights reserved.

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