Journal
INORGANIC CHEMISTRY
Volume 45, Issue 24, Pages 9640-9642Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic061640r
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Pauling's second crystal rule is shown to be able to predict in a general and simple way the distribution of anions in mixed oxyanion systems such as oxynitrides and oxyhalides with diverse compositions and structure types. Results are presented in a plot correlating the charge of the anions obtained from the observed occupancies in crystallographic positions with the calculated bond strength sums for these sites.
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