Journal
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE
Volume 62, Issue -, Pages 953-959Publisher
BLACKWELL PUBLISHING
DOI: 10.1107/S0108768106039309
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High-resolution neutron powder diffraction has been used in order to characterize the order-disorder transition in monoclinic cyclo-octasulphur. Rapid data collection and the novel use of geometrically constrained refinements has enabled a direct and precise determination of the order parameter, based on molecular site occupancies, to be made. The transition is critical and continuous; with a transition temperature, T-c = 198.4 ( 3) K, and a critical exponent, beta = 0.28 (3), which is indicative of three-dimensional ordering. Difficulties encountered as a consequence of the low thermal conductivity of the sample are discussed.
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