4.1 Article Proceedings Paper

The influence of molecular weight distribution on the optimal thermal treatment of poly(3-hexythiophene) based bulk heterojunction photovoltaic cells

Journal

EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS
Volume 36, Issue 3, Pages 295-300

Publisher

EDP SCIENCES S A
DOI: 10.1051/epjap:2006127

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Chlorobenzene cast films of poly(3-hexylthiophene)-blend blend-[6,6]-phenyl C-61 butyric acid methyl ester (P3HT-blend-PCBM) in 1:1 ratios were used in photovoltaic cells with the structure glass/ITO/PEDOT-blend-PSS/P3HT-blend-PCBM/LiF/Al. By varying the molecular weights of the P3HTs from 4500 to 280 000 g mol mol(-1), it was found that P3HT molecular weight distributions had an, important impact on cell characteristics and the most effective annealing temperature required.

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