Alumina-supported Mn(II), Co(II), Ni(II) and Cu(II) N,N-bis(salicylidene)-2,2-dimethylpropane-1,3-diamine complexes:: Synthesis, characterization and catalytic oxidation of cyclohexene with tert-butylhydroperoxide and hydrogen peroxide

New square-planar manganese(II), copper(II), nickel(IT) and cobalt(IT) complexes of a tetradentate Schiff-base ligand N,N-bis(salicylidene)-2,2-dimethylpropane-1,3-diamine, H-2[salpnMe(2)] have been prepared and characterized by elemental analyses, IR, U-V-Vis, conductometric and magnetic measurements. The results suggest that the symmetrical Schiff-base is a bivalent anion with tetradentate N2O2 donors derived from the phenolic oxygen and azomethine nitrogen. The formulae was found to be [M(salpnMe2)] for the 1:1 nonelectrolytic complexes. Alumina-supported metal complexes (ASMC; [M(salpnMe2)/Al2O3]) catalyze the oxidation of cyclohexene with tert-buthylhydroperoxide (TBHP) and hydrogen peroxide. Oxidation of cyclohexene with TBHP gave 2-cyclohexene-1-one, 2-cyclohexene-1-ol and 1-(tert-butylperoxy)-2-cyclohexene whereas, oxidation with H2O2 resulted in the formation of cyclohexene oxide and cyclohexene-1,2-diol. Manganese(11) complex supported on alumina [Mn(salpnMe2]-Al2O3 shows significantly higher catalytic activity than other catalysts. (c) 2006 Elsevier B.V. All rights reserved.