Journal
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
Volume 56, Issue 3-4, Pages 281-285Publisher
SPRINGER
DOI: 10.1007/s10847-006-9110-5
Keywords
carboxylic acid hosts; hydrogen bonding; inclusion crystals; X-ray structure analysis
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The host compounds 1,1'-binaphthyl-2,2'-dihydroxy-5,5'-dicarboxylic acid (1) and 1,1'-binaphthyl-2,2'-dihydroxy-6,6'-dicarboxylic acid (2) have been synthesized, and their inclusion properties have been studied. Inclusion complexes formed by 1 and 2 with volatile guests such as acetone and methanol release the guests only at much higher temperatures than their boiling points. The crystal structures of the inclusion complexes have been determined from single crystal X-ray diffraction data and show different host lattices.
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