Journal
CATALYSIS LETTERS
Volume 112, Issue 3-4, Pages 155-161Publisher
SPRINGER
DOI: 10.1007/s10562-006-0196-6
Keywords
palladium; zinc; heterobimetallic complex; reduction; nanoalloy; EXAFS; XANES; XRD
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The heterobimetallic lantern complex Pd(mu-OOCMe)(4)Zn(OH2) was found to be readily reduced with H-2 under fairly mild conditions (150-250 degrees C, 5-10% H-2/He) both in the carbon-supported and crystalline states to afford a Pd-Zn nanoalloy as evidenced by the ICP elemental analysis, EXAFS, XANES and XRD data.
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