Journal
ADVANCED MATERIALS
Volume 18, Issue 23, Pages 3169-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200601636
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The zero strain Li4+xTi5O12 material as a two-phase system is, in contrast to common knowledge, unstable at room temperature (see figure), and it is fast Li insertion that leads to a kinetically induced effective two-phase reaction. The solid-solution-induced disorder, resulting from the mixed 8a/16c occupation, is most likely responsible for the high rate capabilities in Li4+xTi5O12.
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