Journal
ORGANOMETALLICS
Volume 25, Issue 25, Pages 5965-5968Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om060742m
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Cationic (2a, b) and formally zwitterionic (3a, b) Rh(I) and Ir(I) complexes supported by P, N-substituted indene or indenide ligands (respectively) have been employed in the selective hydroboration of substituted vinylarenes with pinacolborane (HBpin=pin) 1,2-O2C2Me4). Notably, 3a, b exhibited remarkably high, but differing, selectivities in the hydroboration of 1-phenylpropene.
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