4.8 Article

Isocorannulenofuran: A versatile building block for the synthesis of large buckybowls

Journal

ORGANIC LETTERS
Volume 8, Issue 25, Pages 5909-5911

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol0625839

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Isocorannulenofuran, synthesized in two steps from accessible bromocorannulene, gives Diels-Alder adducts with benzynes which can be deoxygenated to produce large polycyclic aromatic hydrocarbons (PAHs) combining the bowl-shaped corannulene subunit with planar fragments.

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