Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 71, Issue 25, Pages 9464-9469Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo061779j
Keywords
-
Categories
Funding
- NIGMS NIH HHS [GM-57052] Funding Source: Medline
Ask authors/readers for more resources
By employing the coupling reaction of trans-PtI2(Et-3)(2) with C-H bonds in alkynes as the key step, two new 60 organometallic subunits with different size from 3,6-dibromophenanthrene were prepared in reasonable yields. The X-ray structures of both di-Pt(II) diiodide complexes showed that they were indeed suitable candidates for 60 building units. By utilizing these novel linkers as ditopic acceptor subunits, three M3L2 trigonal-bipyramidal (TBP) cages were formed. All three TBP cages were characterized with multinuclear NMR and electrospray ionization mass spectrometry (ESI-MS) along with element analysis.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available