Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 24, Pages 5148-5157Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200600771
Keywords
ferrocenes; phospholes; P,P ligands; asymmetric catalysis; X-ray diffraction
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A convenient synthesis of new chiral ferrocenene-bridged phosphole-phosphane ligands in an enantiomerically pure form has been developed. These new chiral PP ligands have been tested in a palladium-catalysed allylic substitution reaction. High activities and moderate enantioselectivities (up to 61 %) were observed. A palladium(II) complex has been isolated and its crystal structure established. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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