Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 128, Issue 50, Pages 16058-16061Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja0622249
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A new pyrrole-based tetraphosphorus ligand capable of forming multiple chelating modes has been prepared. Higher regioselectivity has been achieved in the rhodium-catalyzed isomerization-hydroformylations of internal olefins compared with its bisphosphorus analogue.
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