4.7 Article

Unprecedented formation of a rhodium cluster triggered by rhodium-fastened N-confused gable porphyrin

Journal

INORGANIC CHEMISTRY
Volume 45, Issue 26, Pages 10428-10430

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic061741p

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Thermal reaction of N-confused porphyrin (NCP) with [RhCl(CO)(2)](2) caused unprecedented formation of tetranuclear rhodium complex Rh-4(NCP)(2)(CO)(4) having a gable-porphyrin-type structure, where two porphyrin pi systems were electronically connected by the rhodium cluster.

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