Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 128, Issue 51, Pages 16846-16850Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja0649217
Keywords
-
Categories
Ask authors/readers for more resources
A porous hybrid inorganic/organic material, NaNi3(OH)(SIP)(2) [SIP = 5-sulfoisophthalate] [1], is shown to strongly bind molecular hydrogen at coordinatively unsaturated metal sites. A combination of H-2 sorption isotherms, temperature programmed desorption, and inelastic neutron scattering spectroscopy show the existence of a considerable number of such strong binding sites in [1] along with other sites where hydrogen is more weakly physisorbed. The overall capacity for hydrogen of this material as well as the much stronger binding of hydrogen than in typical porous material represent an important step toward a possible utilization of porous media for hydrogen storage.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available