4.7 Article

Strained azetidinium ylides: new reagents for epoxidation

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 24, Pages 2500-2502

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b701848g

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Azetidinium ylides effected facile epoxidation of various carbonyl compounds furnishing tri or tetrasubstituted epoxides that were unattainable via classical ammonium ylide chemistry; the produced trisubstituted oxiranes gave rise to a remarkable cascade of reactions leading to some original pyrrolidin-3-ones.

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