Journal
CHEMICAL RECORD
Volume 7, Issue 4, Pages 238-253Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.20121
Keywords
ruthenium; isomerization; cycloisomerization; heterocycles; indole
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Non-metathesis reactions of ruthenium carbene catalysts, such as olefin isomerization, hydrogenation, radical reaction, activation of silane, cyclopropanation, epimerization cocyclopropane, [3 + 2] cycloaddition, and cycloisomerization, are summarized. The utility of these reactions was demonstrated by the synthesis of indole using olefin isomerization and subsequent ring-closing metathesis, the synthesis of indoline using cycloisomerization, and the synthesis of the putative structure of fistulosin using cycloisomerization as a key step. (c) 2007 The Japan Chemical Journal Forum and Wiley Periodicals, Inc.
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