Journal
SUPRAMOLECULAR CHEMISTRY
Volume 19, Issue 1-2, Pages 9-15Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610270600879076
Keywords
anion receptors; amides; urea; crystallography
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Two new ortho-phenylenediamine based bis-urea compounds have been synthesized with pendant amide groups. The stability constants of the new compounds with a variety of anionic guests have been measured by (1) H NMR titration techniques and compared to the parent bis-urea. The X-ray crystal structure of the acetate and benzoate complexes of a bis-amide functionalized system have been solved and reveal the receptor forming a dimer with two anions bound at the termini of the hydrogen bonded assembly.
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