4.7 Article

Stereocontrol mechanism in CO/p-methylstyrene copolymerisation catalysed by aryl-α-diimine Pd(II) complexes

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 43, Pages 4540-4542

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b707107h

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Structural analysis of the first steps of isotactic CO/p-methylstyrene copolymerisation, catalysed by aryl-alpha-diimine Pd(II) complexes, highlights the influence of steric effects on the stereoselectivity of olefin insertion.

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