4.7 Article

Tetravalent cerium carbene complexes

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 47, Pages 5037-5039

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b713041d

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Funding

  1. Engineering and Physical Sciences Research Council [GR/S63458/01] Funding Source: researchfish

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The tetravalent organometallic cerium complex [CeL4] is readily accessible from the oxidation of the trivalent [CeL3], L = a bidentate N-heterocyclic carbene alkoxide ligand, [C{(NPri)-CHCHN}CH2CMe2O]. The [CeL4] complex should behave like the [UL4] analogue, but the two complexes show significantly different structures, highlighting the differences between 4f and 5f metals.

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