Journal
BIOINORGANIC CHEMISTRY AND APPLICATIONS
Volume 2007, Issue -, Pages -Publisher
HINDAWI LTD
DOI: 10.1155/2007/51483
Keywords
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Funding
- Principal of Zakir Husain College for providing research facilities
- RSIC
- IIT, Mumbai
- EPR spectra
- DRDO, New Delhi
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A series of metal complexes of Cu(II) and Ni(II) having the general composition [M(L)X-2] with benzil bis(thiosemicarbazone) has been prepared and characterized by element chemical analysis, molar conductance, magnetic susceptibility measurements, and spectral (electronic, IR, EPR, mass) studies. The IR spectral data suggest the involvement of sulphur and azomethane nitrogen in coordination to the central metal ion. On the basis of spectral studies, an octahedral geometry has been assigned for Ni(II) complexes but a tetragonal geometry for Cu(II) complexes. The free ligand and its metal complexes have been tested in vitro against a number of microorganisms in order to assess their antimicrobial properties.
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