Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 31, Pages 3288-3290Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b705034h
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Unexpectedly high reactivity of nitrogenated aromatics protected as amides or carbamates, when compared to sulfonamides, can be explained by a decrease of the aromaticity due to a greater ability of the carbon-centered groups to achieve delocalisation of the nitrogen lone pair, resulting in stronger global withdrawing effects.
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