Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 5, Issue 3, Pages 457-462Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b616621k
Keywords
-
Categories
Ask authors/readers for more resources
Cyclodextrin [ 2] and [ 3] rotaxanes have been synthesised by use of a metal-driven ligand formation methodology. The kinetically stable cobalt(III) complexes formed act as either linking or capping groups, the function being selected by manipulation of the reaction conditions to promote the formation of either 2 : 1 or 1 : 1 complexes, respectively. In all cases, mixtures of isomers containing different alpha-cyclodextrin orientations were observed. All three orientational isomers of the [ 3] rotaxane were isolated and structurally characterized by 2D NMR.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available