4.7 Article

Homoleptic 12-coordinate lanthanoids with η2-nitroso ligands

Journal

DALTON TRANSACTIONS
Volume -, Issue 14, Pages 1371-1373

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b702473h

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The complexes [Et4N](3)[Ln(eta(2)-dcnm)(6)] (Ln = La, Ce, Nd, Gd, dcnm = dicyanonitrosomethanide) have discrete N, O 12-coordination owing to symmetrical chelation of the nitroso donor groups.

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