Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 261, Issue 1, Pages 12-15Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2006.07.057
Keywords
carbon dioxide; epoxides; organic base; stannic chloride; coupling reaction
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A simple and highly efficient catalyst system of SnCl4-organic base was developed to catalyze the coupling reaction of carbon dioxide and epoxides in very mild condition to yield the cyclic carbonates. The proposed mechanism was described in terms of in situ Sn-119 NMR investigations. (c) 2006 Elsevier B.V. All rights reserved.
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