4.8 Article

Singlet biradical character of phenalenyl-based Kekule hydrocarbon with naphthoquinoid structure

Journal

ORGANIC LETTERS
Volume 9, Issue 1, Pages 81-84

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol062604z

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A new Kekule polycyclic hydrocarbon with a singlet biradical index of 50% was synthesized. The singlet biradical character was assessed with UV and H-1-NMR spectroscopy, cyclic voltammetry, SQUID magnetic susceptibility measurement, and quantum chemical calculations.

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