Journal
DALTON TRANSACTIONS
Volume -, Issue 1, Pages 33-36Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b614346f
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The complex cations [RuL2(H(2)biim)](2+) (L = bipy, 4,4'-(t)Bu(2)bipy) interact with cyanometallate anions via a chelating hydrogen-bonding interaction between the two N-H donors of the complex cation and the N lone pair of one cyanide ligand in the complex anion; the anion hexacyanoferrate(III) quenches the Ru(II)-based luminescence in CH2Cl2 solution by photoinduced electron-transfer within the H-bonded assembly, whereas hexacyanocobaltate(III) enhances the Ru(II)-based luminescence.
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