Journal
CHEMICAL PHYSICS
Volume 331, Issue 2-3, Pages 232-244Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.chemphys.2006.10.021
Keywords
photoabsorption; CH(3)Cl; CH(3)I; electronic excitation; vibrational excitation; Rydberg series
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High-resolution photoabsorption spectra of CH(3)Cl and CH(3)I are reported in the energy range 3.9-10.8 eV (320-115 nm). Several features are observed for the first time in the CH(3)Cl spectrum and a number of new assignments are proposed. For both molecules, the present work provides the most reliable absolute cross-sections yet reported at energies above the dissociative A band transition. (c) 2006 Elsevier B.V. All rights reserved.
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