Journal
TETRAHEDRON LETTERS
Volume 48, Issue 2, Pages 297-300Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.11.014
Keywords
chiral cobalt salen; epoxides; Lewis acid; resolution
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Chiral Co(salen) complexes bearing the Lewis acid of group 13 can efficiently catalyze the reactions of carbon dioxide with epoxides in the presence of catalytic amounts of alkali metal salts, quaternary ammonium halide or ionic liquids. They exhibited excellent activity for producing enantiomerically enriched cyclic carbonates. (c) 2006 Elsevier Ltd. All rights reserved.
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