Journal
ANALYTICA CHIMICA ACTA
Volume 581, Issue 2, Pages 202-207Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2006.08.027
Keywords
molecular imprinting; luminescence; organophosphates; controlled polymerization
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Molecularly imprinted polymers capable of sensing organophosphorous compounds by luminescence have been prepared by reversible addition fragmentation chain transfer (RAFT) polymerization. The polymer contained a dithiobenzoate substituted tris(beta-diketonate) europium(III) complex which served as a polymerization substrate and as a luminescent binding site for pinacolyl methylphosphonate (PMP), the hydrolysis product of the nerve agent Soman. The resultant polymer allowed quantitation of PMP in the low ppb range with minimal interference from similar compounds. Polymers were characterized by luminescence spectroscopy and scanning electron microscopy. (c) 2006 Elsevier B.V. All rights reserved.
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