Journal
CHEMISTRY OF MATERIALS
Volume 19, Issue 1, Pages 14-17Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm061902n
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We have synthesized a new azobenzene compound hexahexanoyl 4,4'-dimelaminoazobenzene (He-Diazine-Azo) with self-complementary quadruple hydrogen bonds. The azobenzene in He-Diazine-Azo can undergo trans-cis photoisomerization efficiently. Using such a building block, we prepared azobenzene-containing supramolecular polymer films based on multiple hydrogen bonds. In addition, it is found, interestingly, that surface relief gratings can be laser-induced on such azobenzene-containing supramolecular polymer films. The supramolecular polymer films can keep good stability until 100 degrees C.
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