A novel potentiometric membrane sensor for determination of Co2+ based on 5-amino-3-methylisothiazole

A new poly(vinylchloride) (PVC) membrane electrode for trace level determination of Co2+ ions has been developed based on 5-amino-3-methylisothiazole as an ionophore, o-nitrophenyloctylether as a plasticizer and oleic acid (OA) as a good lipophilic additive. The electrode exhibits a Nernstian slope of 29.5 +/- 0.2 mV/decade in a linear range of 1.0 x 10(-1) to 6.3 x 10(-7) M for Co2+ ions. The detection limit of this electrode is 3.9 x 10(-7) M. It has a fast response time of 12 s and can be used for a period of 4 months without any divergence in potentials. The proposed electrode reveals a good selectivity for Co (II) over a wide variety of other tested cations and could be used in the pH range 3.3-9.0. The electrode was successfully applied as an indicator electrode for the potentiometric titration of cobalt ions with EDTA as well as for the direct determination of Co (H) in real samples. (c) 2006 Elsevier B.V. All rights reserved.