Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 60, Issue 1, Pages 1-51Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970601089200
Keywords
coordination chemistry reactions; kinetics; mechanisms; activation parameters; volume profiles
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Detailed kinetics studies of reactions of coordination compounds in solution have been invaluable in determining the relevant reaction mechanisms. A selection of reports that highlights very recent progress in mechanistic investigations of coordination chemistry is presented. The methods and techniques employed in pursuit of these mechanistic goals are referred to mostly through the latest authoritative reports. Reactions chosen for inclusion are classified according to the comprehensive table of contents. In summary, solvent exchange, ligand substitution, redox reactions, some reactions of nitric oxide and a few other reactions, whose mechanisms have been scrutinised, are covered.
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