Journal
CHEMICAL PHYSICS LETTERS
Volume 433, Issue 4-6, Pages 296-300Publisher
ELSEVIER
DOI: 10.1016/j.cplett.2006.11.077
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Resonance Raman spectra of hydrogen-capped linear carbon molecules, polyynes H(-C equivalent to C-)(n)H (n = 5,6), were measured in n-hexane. For C10H2, the peaks at 2123 cm(-1) and 2017 cm(-1) were identified as the nu(3)(sigma(g)) and nu(4)(sigma(g)) modes in D-infinity h symmetry, respectively. For C12H2, the peaks of nu(3)(sigma(g)) at 2097 cm(-1) and nu(4) (sigma(g)) at 2053 cm(-1) were identified. The relative intensities of the first-order Stokes lines and their resonance enhancement are discussed in terms of the Franck-Condon overlap and resonance absorption relevant to the fully-allowed electronic transition of (1)Sigma(+)(u) <-> (Chi) over tilde (1)Sigma(+)(g). (c) 2006 Elsevier B.V. All rights reserved.
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