Journal
CARBOHYDRATE RESEARCH
Volume 342, Issue 1, Pages 111-118Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2006.10.023
Keywords
imidates; glycosidation; anomerisation; glucuronic acid; amides; Lewis acid
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The synthesis of novel cyclic glycosyl imidates and an investigation of their potential as donors in glycosidation reactions is described. The results show that 1,2-cis glycosides obtained from the reactions of glycosyl acetates or cyclic imidates, each derived from amides of glucuronic acid, result from the anomerisation of initially formed 1,2-trans glycosides. (c) 2006 Elsevier Ltd. All rights reserved.
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