Journal
APPLIED PHYSICS LETTERS
Volume 90, Issue 4, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.2436648
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Lead-free (K0.44Na0.52Li0.04)(Nb0.96-xTaxSb0.04)O-3 piezoelectric ceramics have been synthesized by conventional solid state sintering process. Two morphotropic phase boundaries (MPBs) respectively corresponding to the orthorhombic to tetragonal and tetragonal to pseudocubic phases are observed with increasing x. The ceramics with x=0.20 between the two MPBs show significantly enhanced electrical properties, which are as follows: piezoelectric constant d(33)=252 pC/N, planar coupling coefficient k(p)=0.42, dielectric constant epsilon(r)=1503, and dielectric loss tan delta=0.025, and they show good stability. Lead-free superthin buzzer disks have been prepared by using piezoceramic membrane with x=0.20. (K0.44Na0.52Li0.04)(Nb0.96-xTaxSb0.04)O-3 ceramics are very promising as lead-free replacements for lead zirconate titanate. (c) 2007 American Institute of Physics.
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